石墨烯具有优异的电学、力学和热学性能,过渡金属氧化物具有高的比容量,石墨烯与过渡金属氧化物复合作为电极材料,充分发挥了石墨烯与过渡金属氧化物在电极材料应用方面的优势,在确保高比容量的同时具有良好的导电性能与优异的循环稳定性。综述了过渡金属氧化物/石墨烯复合材料研究进展,首先介绍了过渡金属氧化物/石墨烯复合材料的4种模型结构,即表面固定模型、叠层模型、包裹模型和混合模型,然后从三维纳米结构、杂元素掺杂、使用多元过渡金属氧化物、构建碳壳包裹结构等四方面对过渡金属氧化物/石墨烯复合材料功能化修饰,构建高性能电极材料作了详细分析,最后对过渡金属氧化物/石墨烯复合材料的发展前景作了展望。
Graphene(rGO) has excellent electrical,mechanical and thermal properties,and transition metal oxides with high specific capacity,rGO with metal oxide composite as electrode material,which play the advantage of rGO and metal oxide in the application of electrode materials,ensuring high capacity,good conductivity and excellent cycle stability.The research progress of transition metal oxide and rGO composites was reviewed.Firstly,four kinds of model structures of the composites were introduced,i.e.surface fixation model,stacking model,wrapping model and hybrid model.Then,the composites were further modified from four aspects,i.e.3D nanostructure,doping of miscellaneous elements,using multiple transition metal oxides and constructing carbon shell wrapping structure to build high-performance electrode materials.Finally,the development prospect of the composites was prospected.
[1] Ohzuku T,Iwakoshi Y,Sawai K.Formation of Lithium-graphite intercalation compounds in conaqueous electrolytes and their application as a negative electrode for a lithium ion (shuttlecock) cell[J].ChemInForm,1993,140(9):2490-2497.
[2] Mahmoud A,Amarilla J M,Lasri K,et al.Influence of the synthesis method on the electrochemical properties of the Li4Ti5O12 spinel in Li-half and Li-ion full-cells.a systematic comparison[J].Electrochimica Acta,2013,93:163-172.
[3] Chen Z,Belharouak I,Sun Y K,et al.Titanium-based anode materials for safe lithium-ion batteries[J].Advanced Functional Materials,2013,23(8):959-969.
[4] Idota Y,Kubota T,Matsufuji A,et al.Tin-based amorphous oxide:a high-capacity lithium-ion-storage material[J].Science,1997,276(5317):1395-1397.
[5] Poizot P,Laruelle S,Grugeon S,et al.Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries[J].Nature,2000,407(6803):496-499.
[6] Park C M,Kim J H,Hansu K H K,et al.ChemInform Abstract:Li-alloy based anode materials for Li secondary batteries[J].Chemical Society Reviews,2010,39(8):3115-3141.
[7] Cabana J,Monconduit L,Larcher D,et al.Beyond intercalation-based Li-ion batteries:the state of the art and challenges of electrode materials reacting through conversion reactions[J].Advanced Materials,2010,22(35):E170-E192.
[8] Schedin F,Geim A K,Morozov S V,et al.Detection of individual gas molecules adsorbed on graphene[J].Nature Materials,2007,6(9):652-655.
[9] Dahn J R,Zheng T,Liu Y,et al.Mechanisms for lithium insertion in carbonaceous materials[J].Science,1995,270(5236):590-593.
[10] Junbo H,Yuyan S,Ellis M W,et al.Graphene-based electrochemical energy conversion and storage:fuel cells,supercapacitors and lithium ion batteries[J].Physical Chemistry Chemical Physics,2011,13(34):15384-15402.
[11] Shun M,Ganhua L,Junhong C.Three-dimensional graphene-based composites for energy applications[J].Nanoscale,2015,7(16):6924-6943.
[12] Sun Y M,Hu X L,Wei L,et al.Ultrathin CoO/graphene hybrid nanosheets:a highly stable anode material for lithium-ion batteries[J].Journal of Physical Chemistry C,2012,116(39):20794-20799.
[13] Liu H,Cao K,Xu X,et al.Ultrasmall TiO2 nanoparticles in situ growth on graphene hybrid as superior anode material for sodium/lithium ion batteries[J].ACS Applied Materials Interfaces,2015,7(21):11239-11245.
[14] Lei L,Kovalchuk A,Fei H,et al.Enhanced cycling stability of lithium-ion batteries using graphene-wrapped Fe3O4-graphene nanoribbons as anode materials[J].Advanced Energy Materials,2015,5(14):1500171.
[15] Chen C M,Zhang Q,Huang J Q,et al.Chemically derived graphene/metal oxide hybrids as electrodes for electrochemical energy storage:pre-graphenization or post-graphenization[J].Journal of Materials Chemistry,2012,22(28):13947-13955.
[16] Wu Zhong-Shuai,Ren Wencai,Wen Lei,et al.Graphene anchored with Co3O4 nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance[J].ACS Nano,2010,4(6):3187-3194.
[17] Wang H,Cui L F,Yang Y,et al.Mn3O4-graphene hybrid as a high-capacity anode material for lithium ion batteries[J].Journal of the American Chemical Society,2010,132(40):13978-13980.
[18] Liu J,Huang J,Hao L,et al.SnO2 nano-spheres/graphene hybrid for high-performance lithium ion battery anodes[J].Ceramics International,2013,39(8):8623-8627.
[19] Yang S,Feng X,Ivanovici S,et al.Fabrication of graphene-encapsulated oxide nanoparticles:towards high-performance anode materials for lithium storage[J].Angewandte Chemie,2010,49(45):8408-8411.
[20] Stoller M D,Park S J,Zhu Y W,et al.Graphene-based ultracapacitors[J].Nano Letters,2008,8(10):3498-3502.
[21] Balandin A A,Ghosh S,Bao W Z,et al.Superior thermal conductivity of single-layer graphene[J].Nano Letters,2008,8(3):902-907.
[22] Lee J K,Smith K B,Hayner C M,et al.Silicon nanoparticles-graphene paper composites for Li ion battery anodes[J].Chemical Communications,2010,46(12):2025-2027.
[23] Paek S M,Yoo E,Honma I.Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure[J].Nano Letters,2009,9(1):72-75.
[24] Wang B,Wu X L,Shu C Y,et al.Synthesis of cuo/graphene nanocomposite as a high-performance anode material for lithium-ion batteries[J].Journal of Materials Chemistry,2010,20(47):10661-10664.
[25] Sun H,Mei L,Liang J,et al.Three-dimensional holey-graphene/niobia composite architectures for ultrahigh-rate energy storage[J].Science,2017,356(6338):599-604.
[26] Xu Y,Lin Z,Zhong X,et al.Holey graphene frameworks for highly efficient capacitive energy storage[J].Nature Communications,2014,5:4554-4561.
[27] Xu Y,Chen C Y,Zhao Z,et al.Solution processable holey graphene oxide and its derived macrostructures for high-performance supercapacitors[J].Nano Letters,2015,15(7):4605-4610.
[28] Luo J,Liu J,Zeng Z,et al.Three-dimensional graphene foam supported Fe3O4 lithium battery anodes with long cycle life and high rate capability[J].Nano Letters,2013,13(12):6136-6143.
[29] Li N,Chen Z,Ren W,et al.Flexible graphene-based lithium ion batteries with ultrafast charge and discharge rates[J].Proceedings of the National Academy of Sciences,2012,109(43):17360-17365.
[30] Chen Z,Ren W,Gao L,et al.Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition[J].Nature Materials,2011,10(6):424-428.
[31] Zhang H,Yu X,Braun P V.Three-dimensional bicontinuous ultrafast-charge and-discharge bulk battery electrodes[J].Nature Nanotechnology,2011,6(5):277-281.
[32] Chen J,Wu X,Gong Y,et al.General synthesis of transition metal oxides hollow nanospheres/nitrogen-doped graphene hybrids via metal-ammine complex chemistry for high performance lithium ion batteries[J].Chemistry-A European Journal,2017,24(9):2126-2136.
[33] Jiang Z J,Jiang Z Q.Fabrication of nitrogen-doped holey graphene hollow microspheres and their use as an active electrode material for lithium ion batteries[J].ACS Applied Materials & Interfaces,2014,6(21):19082-19091.
[34] Xing X,Liu R L,Liu S Q,et al.Surfactant-assisted hydrothermal synthesis of cobalt oxide/nitrogen-doped graphene framework for enhanced anodic performance in lithium ion batteries[J].Electrochim.Acta,2016,194:310-316.
[35] Qin G,Zhang H,Wang C.Ultrasmall TiO2 nanoparticles embedded in nitrogen doped porous graphene for high rate and long life lithium ion batteries[J].Journal of Power Sources,2014,272:491-500.
[36] Sanchez J S,Pendashteh A,Palma J,et al.Porous nicomn ternary metal oxide/graphene nanocomposites for high performance hybrid energy storage devices[J].Electrochimica Acta,2018,279:44-56.
[37] Pendashteh A,Palma J,Anderson M,et al.Nanostructured porous wires of iron cobaltite:novel positive electrode for high-performance hybrid energy storage devices[J].Journal of Materials Chemistry A,2015,3(32):16849-16859.
[38] Ashish A G,Arunkumar P,Babu B,et al.TiNb2O7/Graphene hybrid material as high performance anode for lithium-ion batteries[J].Electrochimica Acta,2015,176:285-292.
[39] Liu S,Wang R,Liu M,et al.Fe2O3@SnO2 nanoparticle decorated graphene flexible films as high-performance anode materials for lithium-ion batteries[J].Journal of Materials Chemistry A,2014,2(13):4598-4604.
[40] Zhou W,Cheng C,Liu J,et al.Epitaxial growth of branched α-Fe2O3/SnO2 nano-heterostructures with improved lithium-ion battery performance[J].Advanced Functional Materials,2011,21(13):2439-2445.
[41] Zhang M,Lei D N,Yin X M,et al.Magnetite/graphene composites:microwave irradiation synthesis and enhanced cycling and rate performances for lithium ion batteries[J].Journal of Materials Chemistry,2010,20(26):5538-5543.
[42] Zhou G M,Wang D W,Li F,et al.Graphene-wrapped Fe3O4 anode material with improved reversible capacity and cyclic stability for lithium ion batteries[J].Chemistry of Materials,2010,22(18):5306-5313.
[43] Zhang W M,Wu X L,Hu J S,et al.Carbon coated Fe3O4 nanospindles as a superior anode material for lithium-ion batteries[J].Advanced Functional Materials,2008,18(24):3941-3946.
[44] Balaya P,Li H,Kienle L,et al.Fully reversible homogeneous and heterogeneous Li storage in RuO2 with high capacity[J].Advanced Functional Materials,2003,13(8):621-625.
[45] Jamnik J,Maier J.Nanocrystallinity effects in lithium battery materials[J].Physical Chemistry Chemical Physics,2003,5(23):5215-5220.
[46] Li B J,Cao H Q,Shao J,et al.Enhanced anode performances of the Fe3O4-carbon-rGO three dimensional composite in lithium ion batteries[J].Chemical Communications,2011,47(37):10374-10376.
[47] Jiang X,Yang X L,Zhu Y H,et al.Graphene/carbon-coated Fe3O4 nanoparticle hybrids for enhanced lithium storage[J].Journal of Materials Chemistry A,2015,3(5):2361-2369.
基金资助
广东省市场监督管理局科技项目(2018CZ17);广东省市场监督管理局科技项目(2018PT05)
PDF
